Internal Resistance in Lithium Ion Batteries: What You Need to Know

Lithium-ion battery internal resistance impacts how well the battery works. Learn about what it is, its factors, how to calculate it, and its effects on battery use. Understanding this is key for better efficiency and a longer battery life.

Part 1. What is lithium-ion battery internal resistance?

Ohmic Resistance

Lithium Ion Battery internal resistance encompasses various elements hindering the current flow within the battery. Ohmic resistance, a fundamental component, represents the inherent opposition within the battery’s components. This resistance arises due to the physical properties of the battery materials, including the electrodes, electrolytes, and separators. Ohmic resistance is quantified in ohms and contributes to the voltage drop experienced during current flow.

Polarization Resistance

Another aspect of Lithium Ion Battery internal resistance is polarization resistance. This resistance arises due to the electrochemical processes occurring within the battery during charge and discharge cycles. Polarization resistance involves phenomena such as the movement of ions, charge transfer at electrode interfaces, and concentration polarization within the electrolyte. It impacts energy conversion efficiency within the battery and affects its overall Performance.

Part 2. Factors influencing lithium-ion battery internal resistance

Electrolyte

The composition and conductivity of the electrolyte significantly impact internal resistance. Electrolytes with higher ion conductivity reduce resistance, allowing smoother ion movement between electrodes. Conversely, less conductive electrolytes increase internal resistance, impeding ion flow and affecting battery performance.

Diaphragm

The diaphragm or separator within the battery influences internal resistance by controlling ion movement. Its permeability and structure impact the resistance by facilitating or restricting the passage of ions between electrodes. Optimized diaphragm design can lower resistance and enhance battery efficiency.

Collector

The material and design of the current collector affect internal resistance. Proper collector design ensures efficient electron transfer between electrodes, minimizing resistance. Materials with high conductivity, such as copper or aluminum, can reduce resistance by aiding electron flow.

Current

The magnitude and direction of the current passing through the battery affect internal resistance. Higher currents can lead to increased resistance due to factors like heat generation and changes in ion mobility within the battery’s components.

Temperature

Temperature variations play a critical role in internal resistance. Low temperatures increase resistance by restricting ion movement, impacting battery performance. Conversely, high temperatures might lower resistance but can accelerate degradation processes, affecting long-term resistance.

Manufacturing Process

The battery manufacturing process influences internal resistance. Factors like electrode thickness, material quality, assembly techniques, and quality control measures impact the uniformity of the battery’s components, subsequently affecting internal resistance. Well-optimized manufacturing processes can result in lower internal resistance and enhanced battery performance.

Part 3. How does internal resistance affect performance?

Voltage Output and Sag

Internal resistance significantly influences a battery’s ability to maintain a steady voltage output when powering a device. For instance, in a smartphone with a Lithium Ion Battery exhibiting high internal resistance, when the device experiences heavy usage (like gaming or video streaming), the battery voltage might sag noticeably, causing the device to shut down or prompt a low battery warning prematurely.

Efficiency and Energy Loss

Consider an electric vehicle (EV) powered by a lithium-ion battery with increased internal resistance. The higher resistance leads to energy loss as heat during charge and discharge cycles. This lost energy, instead of contributing to the vehicle’s propulsion, dissipates as heat, reducing the overall efficiency of the EV and decreasing its driving range per charge.

Capacity and Run Time

The adequate capacity diminishes in a laptop utilizing a Lithium Ion Battery with elevated internal resistance. The battery’s capacity decreases as the resistance increases, affecting the laptop’s run time between charges. This reduced usable capacity shortens the device’s operational duration, requiring more frequent recharging.

Heat Generation and Battery Health

Consider a power tool powered by a Lithium Ion Battery with increased internal resistance. The higher resistance causes more heat to be generated during high-demand tasks. This excessive heat accelerates battery degradation, reducing its lifespan. Over time, the tool’s battery loses its ability to hold a charge. It becomes prone to failure due to increased internal resistance-induced heat stress.

Part 4. How do you calculate the internal resistance of a battery cell?

1. Voltage Drop Method

One approach to calculating internal resistance involves the voltage drop method. Start by measuring the open-circuit voltage of the battery. Then, apply a known load (a resistor or device with a general resistance) to draw current from the battery. Measure the voltage across the battery terminals while the load is connected and drawing current. Using Ohm’s Law (R = V/I), where R is resistance, V is voltage. I is current; you can calculate the internal resistance (R = V / I), where V is the change in voltage, and I is the change in current caused by the load.

2. AC Impedance Spectroscopy

Another method involves using AC impedance spectroscopy. This technique applies an AC signal across the battery terminals at varying frequencies. By analyzing the impedance response of the battery to these frequencies, particularly at low and high frequencies, you can extract information about the battery’s internal resistance and other electrochemical properties.

3. Pulse Discharge Method

The pulse discharge method is also utilized for internal resistance calculation. Apply a short, high-current pulse to the battery and measure the voltage drop during this pulse. Analyze the voltage change over time to determine the internal resistance. This method is beneficial for quick assessments but requires careful consideration of the pulse’s duration and intensity to avoid damaging the battery.

4. Data Analysis and Curve Fitting

Advanced techniques involve collecting discharge curves from the battery. You can perform curve fitting or regression analysis to extract the internal resistance by analyzing the voltage versus time data during discharge under various loads. This method provides a more detailed insight into resistance variations across different operating conditions.

5. Simulation and Modeling

Simulations can use specialized software or battery modeling tools to predict internal resistance based on battery specifications, materials, and operating conditions. These simulations consider factors like electrode composition, electrolyte properties, and temperature to estimate internal resistance without physically testing the battery.

Part 5. FAQs

John

Lithium Battery Content Writer

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